@article {1697, title = {Photoassociation of spin polarized Chromium}, journal = {Physical Review A}, volume = {93}, year = {2016}, month = {2016/02/29}, pages = {021406}, abstract = {We report the homonuclear photoassociation (PA) of ultracold 52Cr atoms in an optical dipole trap. This constitutes the first measurement of PA in an element with total electron spin S~>1. Although Cr, with its 7S3 ground and 7P4,3,2 excited states, is expected to have a complicated PA spectrum we show that a spin polarized cloud exhibits a remarkably simple PA spectrum when circularly polarized light is applied. Over a scan range of 20 GHz below the 7P3 asymptote we observe two distinct vibrational series each following a LeRoy-Bernstein law for a C3/R3 potential with excellent agreement. We determine the C3 coefficients of the Hund{\textquoteright}s case c) relativistic adiabatic potentials to be -1.83{\textpm}0.02 a.u. and -1.46{\textpm}0.01a.u.. Theoretical non-rotating Movre-Pichler calculations enable a first assignment of the series to Ω=6u and 5g potential energy curves. In a different set of experiments we disturb the selection rules by a transverse magnetic field which leads to additional PA series.}, doi = {10.1103/PhysRevA.93.021406}, url = {http://arxiv.org/abs/1512.04378}, author = {Jahn R{\"u}hrig and Tobias B{\"a}uerle and Paul S. Julienne and Eite Tiesinga and Tilman Pfau} }